Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction

نویسندگان

  • Mathias Lang
  • Alexandra Schade
  • Stefan Bräse
چکیده

Herein we report the syntheses of two porous hyper-crosslinked polymers (HCPs) via thiol-yne reaction with rigid tetrahedral and pseudo-octahedral core structures. Sorption measurements with nitrogen gas at 77 K revealed BET-surface areas up to 650 m²/g. Those networks also showed a high thermal stability as well as insolubility in common organic solvents.

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عنوان ژورنال:

دوره 12  شماره 

صفحات  -

تاریخ انتشار 2016